Purple coloring in insulators is caused by the
addition of manganese,
a de-colorizer originally used to remove the green or aqua cast
caused by the iron inevitably found in batch sand (all glass colorants
are metals or metal oxides). After exposure to radiation-- either
natural solar or artificial-- the manganese ionizes to a purple form;
the more manganese, the darker the purple eventually becomes. If too
much manganese is added initially, the glass starts out purple, then
turns darker still, hence "royal purple". The manganese used in
insulator production once came mostly from Germany. When World War I
broke out, the supply was cut off, and selenium was used instead.
Selenium glass also "solarizes", but turns a
straw color.
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